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Cafe Lux was my favorite cafe, as it is not as 'trendy', crowded or full of obnoxious people as Cafe M (which is next door). Good breakfast (9 a.m. - 3 p.m.), nice sightseeing (guests), decent beer & drinks prices. Recommended.
Subway Eisenacher Strasse or Nollendorfplatz
Open daily 9 a.m. - 2 a.m.